Synthesis of polycylic compounds related to steroids XIII. Reaction of carbocyclic ketones with 1-acetyl-1-cyclohexene |
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| Authors: | I. N. Nazarov S. I. Zavyalov |
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| Affiliation: | (1) Institute of Organic Chemistry of the USSR Academy of Sciences, USSR |
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| Abstract: | Summary The condensation has been carried out of 1-decalone (III), 8a-methyl-1-octalone (V), and 3a,4,7,7a-tetrahydro-3,7a-dimethyl-1-indanone (VI) with 1-acetyl-1-cyclohexene. The products were the polycyclic kiketones VII, IX, and XI, which under the conditions of the experiment did not undergo a further intramolecular crotonic condensation. |
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