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Influence of Adding SiO2 into ZrO2 on SO2-4/ZrO2 Solid Superacid
Abstract:A series of SO2-4/ZrO2-SiO2 catalysts with different SiO2 amount were prepared by coprecipitation and coating methods. The effect of adding SiO2 into ZrO2 on the crystallization, surface area, sulfur content, superacidity of SO2-4/ZrO2 and cumene cracking and iso-propanol dehydration was studied in detail. Adding SiO2 into ZrO2 retarded the crystallization and phase transformation of ZrO2, and decreased solid superacidity of SO2-4/ZrO2, but enhanced the catalytic activities of SO2-4/ZrO2 for cumene cracking and iso-propanol dehydration.
Keywords:Solid superacidity  SO
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