Isomerism in metal complexes of 1,3,5-diazaphosphorinanes. Synthesis,crystal and molecular structure of conformers ofcis-bis(1,3,5-triphenyl-1,3,5-triazaphosphorinane)dichloroplatinum(II) |
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| Authors: | A A Karasik S V Bobrov G N Nikonov I A Litvinov V A Naumov A G Akhmadullin |
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| Institution: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420083 Kazan', Russian Federation |
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| Abstract: | The crystal and molecular structures were determined for two individual conformers ofcis-bis(1,3,5-triphenyl-1,3,5-diazaphosphorinane)dichloroplatinum(II) differing in the rotation of the heterocyclic ligand planes around the P-Pt bond and in the orientation of the substituents at the phosphorus atoms in the ligands.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1650–1655, September, 1993. |
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| Keywords: | metal complexes of 1 3 5-diazaphosphorinanes isomerism synthesis crystal and molecular structure |
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