Synthesis and Crystal Structure of a Nickel(Ⅱ) Complex [Ni(H2btc)2(hmta)2(H2O)] with 1,3,5-Benzenetricarboxylate and Hexamethylenetetramine |
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引用本文: | 林鸿,冯云龙.Synthesis and Crystal Structure of a Nickel(Ⅱ) Complex [Ni(H2btc)2(hmta)2(H2O)] with 1,3,5-Benzenetricarboxylate and Hexamethylenetetramine[J].结构化学,2005,24(5):573-576. |
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作者姓名: | 林鸿 冯云龙 |
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作者单位: | Jinhua Professional-technical College,Jinhua 321017,China,Institute of Physical Chemistry,Zhejiang Normal University,Jinhua 321004,China |
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摘 要: | 1 INTRODUCTION Organic-inorganic hybrid material has captured the imaginations of chemists due to its potential applications in electric conductivity, magnetism, ion exchange and catalysis1~2]. Coordination polymers with special structures have been well prepared by the reaction of transition metal ions and special orga- nic ligands. As a kind of multi-dentate ligand, aro- matic polyoxybiontic anion can coordinate with metal ion to form chain, layer and network struc- tures3~6]. 1,3,5…
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关 键 词: | with and Crystal Complex complex Ni(Ⅱ) system the space group final ideal The H2O DMF was for ion one can to |
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