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Preparation of crack‐free nano‐crystalline yttria‐stabilized zirconia
Authors:Harald Drings  Ulrich Brossmann  Hans‐Eckhardt Schaefer
Institution:1. Institute for Theoretical and Applied Physics, University of Stuttgart, Pfaffenwaldring 57, 70550 Stuttgart, GermanyPhone: +49 711 685 65188, Fax: +49 711 685 65271;2. Institute for Materials Physics, Technical University of Graz, Petersgasse 16, 8010 Graz, Austria;3. Institute for Theoretical and Applied Physics, University of Stuttgart, Pfaffenwaldring 57, 70550 Stuttgart, Germany
Abstract:In recent research and development, yttria‐stabilized zirconia have become increasingly important for many industrial applications such as gas sensors and solid oxide fuel cells. In many of these applications, the suppression of uncontrolled gas transport due to porosity or cracks is essential. In this work, the influence of the sintering parameters on the crack formation in n‐ZrO2·9.5 mol% Y2O3, manufactured by room‐temperature compaction of sputtered ZrY nanocrystallites with subsequent oxidation and sintering, was studied. A procedure that enables the production of nearly crack‐free fully dense samples is presented. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
Keywords:66  30  Pa  68  35  Ct  81  07  Bc  81  20  Ev
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