Hydrogen Bonds in Rubidium Amide‐Ammonia(3/2), RbNH2·2/3NH3 |
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| Authors: | Thomas Scheubeck Nikolaus Korber Prof Dr |
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| Institution: | 1. Regensburg, Institut für Anorganische Chemie der Universit?t;2. Regensburg, Institut für Anorganische Chemie der Universit?tInstitut für Anorganische Chemie der Universit?t Regensburg, Universit?tsstra?e 31, D‐93053 Regensburg, Tel.: +49 943 4448, Fax: +49 943 1812 |
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| Abstract: | Rubidium amide‐ammonia(3/2), RbNH2·2/3NH3, was synthesized from Rubidiumhydride, RbH, in liquid ammonia at ?78 °C. The compound crystallizes in the cubic space group I213 with Z = 4, a = 10.0490(12) Å, and V = 1014.77(20) Å as isometric colorless crystals. The crystal structure was solved from single‐crystal X‐ray data. The structure contains a three‐dimensional network of amide anions and ammonia molecules, which are interconnected via hydrogen bonds. |
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| Keywords: | Rubidiumamide Ammoniates Crystal structures Liquid ammonia Hydrogen bonds |
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