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o-Semiquinonic PCP-pincer nickel complexes with alkyl substituents: versatile coordination sphere dynamics |
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| Authors: | Kozhanov Konstantin A Bubnov Michael P Cherkasov Vladimir K Vavilina Nina N Efremova Larisa Yu Artyushin Oleg I Odinets Irina L Abakumov Gleb A |
| Affiliation: | G. A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, Tropinina str., 49, Nizhny Novgorod, 603950, Russia. kostik@iomc.ras.ru |
| Abstract: | o-Semiquinonic nickel pincer complexes (R2PCP)Ni(SQ) show a versatile coordination sphere dynamics via "swing" or "fan" oscillations depending on the steric properties of the phosphorus substituents. |
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