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LaOBr:Tb3+,Dy3+的发光特性及高压研究
引用本文:杨景海,李永吉.LaOBr:Tb3+,Dy3+的发光特性及高压研究[J].高压物理学报,1996,10(3):182-189.
作者姓名:杨景海  李永吉
作者单位:四平师范学院固体物理研究所(杨景海),四平教育学院(李永吉)
基金项目:国家教委优秀年轻教师基金
摘    要: 采用高温常压方法合成了稀土发光材料LaOBr:Tb3+,Dy3+,采用高温高压方法对材料进行了处理,研究了高温高压处理前后样品发光特性的变化,并进行了发光衰减测量。结果表明,Dy3+的掺杂可以将Tb3+5D3能级的激发能有效地驰豫到5D4能级,从而使5D4~7FJ(J=0, 1,…,6)的发射,尤其是5D4~7F5的发射明显增强,使得样品的发光亮度大大提高。Dy3+,Tb3+间存在交叉驰豫共振能量传递。高压处理过程引入的杂质、材料氧化及压致晶场变化都对材料的发光特性产生影响。

关 键 词:高温高压  稀土发光  能量传递
收稿时间:1995-12-20;

The Luminescence Properties and High Pressure Research of LaOBr:Tb3+, Dy3+
YANG Jing-Hai,LI Yong-Ji.The Luminescence Properties and High Pressure Research of LaOBr:Tb3+, Dy3+[J].Chinese Journal of High Pressure Physics,1996,10(3):182-189.
Authors:YANG Jing-Hai  LI Yong-Ji
Institution:1. Institute of Solid State Physics, Siping Normal College, Siping 136000, China;2. Siping Teacher's College, Siping 136000, China
Abstract:The rare earth luminescence materials LaOBr:Tb3+, Dy3+ were synthesized at high temperature, and were treated by high pressure (HP) combined with high temperature (HT). The luminescent properties of the samples before and after HP and HT treatment were studied. The results show that codoping Dy3+ makes the luminescence strength increased greatly, and energy transfer takes place between Tb3+ and Dy3+.
Keywords:high pressure and high temperature  rare earth luminescence  energy transfer
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