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Photomagnetic effect in a cyanide-bridged mixed-valence {Fe(II)2Fe(III)2} molecular square |
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| Authors: | Mondal Abhishake Li Yanling Herson Patrick Seuleiman Mannan Boillot Marie-Laure Rivière Eric Julve Miguel Rechignat Lionel Bousseksou Azzedine Lescouëzec Rodrigue |
| Institution: | Institut Parisien de Chimie Moléculaire, Université Pierre et Marie Curie-Paris 6, UMR 7201, F-75252 Paris Cedex 05, France. |
| Abstract: | The self-assembly of Fe(III)(Tp)(CN)(3)](-) and Fe(II)(bik)(2)(S)(2)](2+) affords the cyanide-bridged mixed valence {Fe(III)(2)Fe(II)(2)}(2+) molecular square, which exhibits a photomagnetic effect under laser light irradiation at low temperature and also shows thermal spin-state conversion near ambient temperature. |
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