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Vaporization energy change and vibrational frequency shift in substituted mono-halo-benzenes
Authors:J. Lielmezs  J. B. Butler  H. C. Henry  R. G. Orr
Affiliation:(1) Department of Chemical Engineering, The University of British Columbia, Vancouver, B.C., Canada;(2) Royal Canadian Navy, Victoria, B.C., Canada;(3) Imperial Oil Enterprises Ltd., Sarnia, Ontario, Canada
Abstract:Direct linear relation exists between the reduced vaporization energy change (DeltaHv/RTB) of benzene and its homologues, C6H5X (X=F, Cl, Br, I) and the X-sensitive dimensionless frequency (hcv/kTB) at their respective normal boiling point (TB) temperatures.The financial assistance of the National Research Council of Canada, the Graduate Fellowship (J.B.B.), the University of British Columbia, and the NRC Bursaries (H.C.H., R.G.O.) are gratefully acknowledged.
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