| Synthesis,Crystal Structure and Luminescent Property of a Novel Pt（Ⅱ） Complex with Weak Metal-metal Interaction |
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| 作者姓名： | YUE Cheng-Yang, JIANG Fei-Long, FENG Rui, HONG Mao-Chun |
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| 作者单位： | State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Department of Chemistry，Jining University |
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| 基金项目： | This work was supported by 973 Program （2006CB932900）, National Natural Science Foundation of China （No. 20571074）, and Natural Science Foundation of Fujian Province （No. 2007J0172） |
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| 摘 要： | The title complex cis-bis（tetrahydrothiophene）-bis（nitrate） platinum（H）, （tht）2Pt（NO3）2, was the reducing product from potassium hexachloroplatinate（IV） K2PtC16 where the platinum is tetra-valenced. Crystal data for CsH16N206PtS2： monoclinic, space group P21/c, a = 9.8833（5）, b = 8.6744（4）, c = 18.6407（9）A,β = 114.401（3）°, V = 1455.35（12）A3 Z = 4, Mr = 495.44, Dc = 2.261 g/cm3, F（000） = 944,μ = 9.950 mm-1, 2（MoKa） = 0.71073 A, T= 293（2） K, 2θmax = 54.96°, GOOF = 1.033, R = 0.0350 and wR = 0.0785 for 2572 observed reflections with I 〉 2σ（I）. X-ray diffraction studies reveal that the title complex has interesting weak metal-metal interactions and two molecules linked by metal-metal interaction exist as a group. Luminescent spectrum illuminates red emission of the complex at room temperature.
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| 关 键 词： | 铂金 发光检测 金属元素 含量 化学分析 |
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