Luminescence of salts and copolymers containing the (MoII6Cl8)4+ cluster |
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| Authors: | Adamenko O A Loukova G V Smirnov V A |
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| Institution: | (1) Russian Academy of Sciences, Institute of Problems of Chemical Physics, 14 Institutskii prosp., 142432 Chernogolovka, Moscow Region, Russian Federation |
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| Abstract: | The photophysical properties (absorption, emission) of the (Bu4N)2(MoII
6Cl8)L6] (L = CF3COO–, CH2=CHCOO–) cluster salts and (Bu4N)2(MoII
6Cl8)(CF3COO)6–n]—polyacrylic acid copolymers were studied. Both the cluster-containing monomers and corresponding copolymers phosphoresce intensely (  0.2—0.4 ms at 77—300 K). |
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| Keywords: | molybdenum clusters cluster-containing polymer charge transfer luminescence |
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