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A Mixed Ruthenium Polypyridyl Complex Containing a PEG‐Bipyridine Macroligand
Authors:Veronica Marin  Elisabeth Holder  Michael A R Meier  Richard Hoogenboom  Ulrich S Schubert
Abstract:Summary: An amino‐functionalized bipyridine ligand was prepared in order to serve as a bridging unit to an activated low‐molecular‐weight monomethyl ether of poly(ethylene glycol) (PEG). Coordination of a ruthenium(II ) phenantroline precursor onto the formed PEG‐containing bipyridine ligand yielded a metal‐containing polymer which shows interesting properties for solar cell applications.
image

A schematic of the described polymeric ruthenium(II ) complex and its absorption and emission properties.

Keywords:functionalized bipyridine ligands  luminescence  macroligand  metal‐containing polymers  poly(ethylene glycol)  ruthenium(II) polypyridyl complexes
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