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Nanostructured Crosslinkable Micropatterns by Amphiphilic Dendrimer Stamping
Authors:Neeraj Kohli  Petar R Dvornic  Steven N Kaganove  Robert M Worden  Ilsoon Lee
Abstract:Summary: Microcontact printing was used to deposit stable, nanostructured, amphiphilic and crosslinkable patterns of poly(amidoamine organosilicon) (PAMAMOS)‐dimethoxymethylsilyl (DMOMS) dendrimer multilayers onto silicon wafers, glass, and polyelectrolyte multilayers. The effects of dendrimer ink concentration, contact time, and inking method, on the thickness, uniformity, and stability of the resulting patterns were studied using optical microscopy, fluorescence microscopy, atomic force microscopy (AFM), and contact‐angle analysis. Microarrayed dendrimer film thickness was found to be controllable by conditions used during spin self‐assembly.

Optical micrograph of the circular patterns, obtained from a 0.5% PAMAMOS dendrimer solution, on a glass substrate.

Keywords:amphiphilic  crosslinking  dendrimers  microcontact printing  spin self‐assembly
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