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Determination of ultra-trace rare earth elements in chondritic meteorites by inductively coupled plasma mass spectrometry
Institution:1. V.S. Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, pr. Akademika Koptyuga 3, Novosibirsk, 630090, Russia;2. Diamond and Precious Metal Geology Institute, Siberian Branch of the Russian Academy of Sciences, pr. Lenina 39, Yakutsk, 677980, Russia;3. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia;1. V.S. Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, pr. Akademika Koptyuga 3, Novosibirsk, 630090, Russia;2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia;1. Dipartimento di Geoscienze, Università di Padova, Via Gradenigo 6, I-35131 Padova, Italy;2. Dipartimento di Scienze della Terra e dell''Ambiente, Università di Pavia, Via Ferrata 1, I-27100 Pavia, Italy;3. Swiss Light Source, Villigen, Switzerland;4. Diamond Light Source Ltd., Harwell Science & Innovation Campus, Didcot, Oxfordshire OX11 0DE, UK;5. Institute for Planetary Materials, Okayama University, Yamada 827, Misasa, Tottori 682-0193, Japan;6. School of Geographical and Earth Sciences, University of Glasgow, G12 8QQ Glasgow, UK
Abstract:A method for the direct determination of ultra-trace rare earth elements (REE) in seven Chinese chondritic meteorites by inductively coupled plasma mass spectrometry (ICP-MS) was developed. Samples were digested with a mixture of HF+HNO3 acids in Teflon pressure bomb. The accuracy and precision of the method were assessed by the analysis of four standard reference materials including one chondrite (Allende) and three basalts (BCR-1, BHVO-1 and W-2), the results obtained in this study agree quite well with the recommended values. The reproducibilities (expressed as RSD) of samples were less than 5%.
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