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Synthesis and Properties of a Novel Thiophene‐Based Conducting Copolymer with Mesogenic Groups Attached Parallel to the Polymer Backbone
Authors:John W. Brown  Gillian J. Lambe  Peter J. S. Foot  Jacqueline A. Clipson
Abstract:Summary: A novel thiophene‐based conducting copolymer has been synthesised with mesogenic groups attached parallel to the conducting polymer backbone; preliminary data are reported on its properties. These indicate that as the nonmesogenic intermediate polymer is converted into a liquid‐crystalline polymer there is a significant increase in conductivity. Measurement of the temperature‐dependent conductivity indicates a reduction of the activation energy in the liquid‐crystalline phase.

Poly[(1‐(thiophene‐3‐methyloxy)‐6‐(4‐n‐hexyloxy‐2‐oxybenzoic acid)hexane)‐co‐(3‐n‐hexylthiophene)].

Keywords:liquid‐crystalline polymers (LCP)  parallel attached  polythiophene  sideways attached  synthesis
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