Determination of selenium in biological tissue samples rich in phosphorus using electrothermal atomization with Zeeman-effect background correction and (NH4)3RhCl6+citric acid as a mixed chemical modifier |
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Institution: | 1. 2;2. Mineral Economics Department, Korea Institute of Geosciences and Mineral Resources, 124 Gwahang-no, Yuseong-gu, Daejeon 305-350, Republic of Korea |
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Abstract: | Spectral interferences from phosphorus on the determination of selenium in biological tissue materials were not observed when a Zeeman-effect background correction was used with rhodium as a chemical modifier. A suppression effect on the selenium signal resulted when the concentration of phosphorus present was greater than 1.0 mg ml?1. Rhodium was found to be more effective than palladium in overcoming the phosphate interference. Analytical procedures for the direct determination of trace selenium in standard reference materials by graphite furnace atomic absorption spectrometry following sample dissolution in nitric acid and hydrogen peroxide using a microwave oven has been described. The results obtained agreed favourably with the certified values. |
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