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Aerobic oxidation of oct-1-ene in a nanoscale microreactor
Authors:Á  gnes Zsigmond  Ferenc Notheisz
Affiliation:(1) Department of Organic Chemistry and Organic Catalysis Research Group of the Hungarian Academy of Sciences, University of Szeged, 6720 Szeged, Dóm tér 8, Hungary
Abstract:Nanoscale microreactors containing the Pd(II)/Pd(0)–1,4-benzoquinone/hydroquinone–CoSalophen OX/ CoSalophen triple catalytic system were constructed in the supercages of zeolite Y. This catalytic system works as a closed reactor and is capable for the highly selective palladium-catalyzed oxidation of oct-1-ene to octan-2-one with molecular oxygen at room temperature.
Keywords:Encapsulated catalysts  zeolite Y  aerobic oxidation  Pd-catalyzed oxidation
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