Electrochemically activated reaction of nucleophilic substitution in polyfluorovinyl halides under the action of the cyclopentadienylirondicarbonyl anion [CpFe(CO)2]? |
| |
| Authors: | I I Kukhareva T V Magdesieva G A Artamkina I P Beletskaya K P Butin |
| |
| Institution: | (1) Department of Chemistry, M. V. Lontonosov Moscow State University, Vorob'evy Gory, 119988 Moscow, Russian Federation |
| |
| Abstract: | The reaction of polyfluorovinyl halides RCF=CFX (R =t-C4F9, X = F, CI, or Br; R = Ph, X = F, Cl) with the CpFe(CO)2]– anion has been studied by cyclic voltammetry and preparative-scale electrolysis. The electrochemical activation of vinyl halides made it possible to obtain the products of nucleophilic substitution for all substrates investigated independently of their configuration and the nature of the halogen.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1523–1528, June, 1996. |
| |
| Keywords: | polyfluorovinyl halides cyclopentadicnylirondicarbonylate anion cyclic voltammetry preparative-scale electrolysis |
| 本文献已被 SpringerLink 等数据库收录！ |
|
