The vibrational ground state rotational spectroscopic constants and structure of the HCN dimer |
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| Authors: | LW Buxton EJ Campbell WH Flygare |
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| Institution: | Noyes Chemical Laboratory, University of Illinois, Urbana, Illinois 61801, USA |
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| Abstract: | Rotational spectra have been assigned for four isotopic species of the linear HCN dimer in the vibrational ground state. The spectroscopic constants are | isotope | -B0 (MHz) | DJ (kHz) | xN1 (MHz) | xN2 (MHz) | | HC14N-HC14N | 1745.80973(50) | 2.133(30) | ?4.0973(200) | ?4.4400(190) | | HC14N-HC15N | 1700.30190(30) | 1.939(40) | ?4.1059(10) | - | | HC15N-HC14N | 1729.92082(20) | 2.023(30) | - | ?4.4339(6) | | HC15N-HC15N | 1684.28825(25) | 1.900(30) | - | - |
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