The electronic spectrum of hydrogen fluoride (7–46 eV) |
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| Authors: | AP Hitchcock CF Brion |
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| Institution: | Department of Chemistry, McMaster University, Hamilton, Canada, L85 4M1;Department of Chemistry, University of British Columbia, Vancouver, Canada, V6T 1Y6 |
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| Abstract: | The electron energy loss spectrum of HF between 7 and 46 eV has been studied with forward, inelastic scattering of 2.5 keV electrons at resolutions up to 60 meV fwhm. The (1π?t, 4σ)A 1Π state of HF has been identified at 10.35 eV (vertical). An apparently prominent progression, observed in optical studies and assigned to the (3σ?1, 4σ)B 1Σ+ state, was not detected in this work. A reasonably complete assignment of the Rydberg structure of HF is proposed. |
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