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Synthesis of degraded cyanogenic glycosides from Sambucus nigra
Authors:Dellagreca Marina  Fiorentino Antonio  Monaco Pietro  Previtera Lucio  Temussi Fabio  Zarrelli Armando
Institution:Dipartimento di Chimica Organica e Biochimica, Università Federico II, Complesso Universitario Monte S. Angelo, Via Cinthia, 1-80134 Napoli, Italy.
Abstract:Two natural cyanohydrins, isolated from Sambucus nigra, have been synthesised from mandelonitrile and penta-O-acetyl-beta-galactopyranose. The synthesis confirmed the stereochemistry of the compounds, which had been assigned on biogenetic grounds.
Keywords:
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