Tris-[3-hydroxy-1,2-dimethyl-pyridin-4(1H)-onato]cobalt(III) |
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| Authors: | Burgess John Fawcett John Llewellyn Mark A Parsons Simon A Russell David R |
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| Institution: | (1) Chemistry Department, University of Leicester, Leicester, LE1 7RH, UK |
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| Abstract: | The preparation and properties of tris-3-hydroxy-1,2-dimethyl-pyridin-4(1H)-onato]cobalt(III) are described. The structure of the fac isomer has been established by X-ray diffraction techniques. Solvation characteristics of this complex have been assessed through solubility measurements in methanol–water mixtures. The complex is very inert in neutral solution but undergoes acid-catalysed aquation at lower pHs. |
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