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Palladium - catalyzed dimerization of propene |
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| Authors: | Gomboo Myagmarsuren Vitalii S Tkach Dmitrii S Suslov and Fedor K Shmidt |
| Institution: | (1) National University of Mongolia, Ulaanbaatar, 210646 Mongolia;(2) Irkutsk State University, Irkutsk, 664003 Russia;(3) Irkutsk State University, Irkutsk, 664003 Russia;(4) Irkutsk State University, Irkutsk, 664003 Russia |
| Abstract: | Summary The insertion of the previously coordinated second molecule of propene into the Pd-C bond is the rate-determining step in the dimerization of propene with the Pd(acac)2 + BF3OEt2 catalyst system. Tetracoordinated square planar Pd hydrides bearing two vacant coordination sites are likely to be catalytically active species in the dimerization of propene. The simplicity of the catalyst system composition might be of industrial importance. |
| Keywords: | palladium propene Dimerization |
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