| CdZnTe晶体位错处的Raman光谱及PL谱研究 |
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| 引用本文： | 曾冬梅,周海,殷业财.CdZnTe晶体位错处的Raman光谱及PL谱研究[J].人工晶体学报,2012,41(4):922-925. |
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| 作者姓名： | 曾冬梅 周海 殷业财 |
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| 作者单位： | 北京石油化工学院材料科学与工程系,北京,102617;北京石油化工学院工程教育中心,北京,102617 |
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| 基金项目： | 国家自然科学基金(青年基金)(51002012) |
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| 摘 要： | 利用显微Raman光谱技术,对比研究了CdZnTe晶体无位错区和位锘密集区的Raman光谱.研究发现,CdZnTe晶体无位错区的Raman光谱出现了与Te有关的A1模(119 cm-1)、类CdTe的TO1模(138 cm-1)和类ZnTe 的TO2模(179 cm-1)；CdZnTe晶体位错密集区的Raman光谱中仅出现了与Te有关的A1模和类CdTe的TO1模,CdZnTe晶体类ZnTe的TO2模消失.对CdZnTe试样位错密集区进行变温光致发光谱测试,结果表明,束缚在中性施主上的激子的离解为电子空穴对,电子空穴的非辐射复合过程吸收了类ZnTe的TO2模声子能量,造成Raman 光谱中类ZnTe的TO2模缺失.
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| 关 键 词： | CdZnTe 位错 Raman光谱 |
Raman and Photoluminescence Study on Dislocations in CdZnTe Crystal |
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| ZENG Dong-mei
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ZHOU Hai
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YIN Ye-cai.Raman and Photoluminescence Study on Dislocations in CdZnTe Crystal[J].Journal of Synthetic Crystals,2012,41(4):922-925. |
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| Authors: | ZENG Dong-mei ZHOU Hai YIN Ye-cai |
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| Institution: | 1.Department of Materials Science and Engineering,Beijing Institute of Petrochemical Technology,Beijing 102617,China 2.Engineering Education Center,Beijing Institute of Petrochemical Technology,Beijing 102617,China) |
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| Abstract: | The Raman spectra were acquired in CdZnTe crystal in both dislocation free zone and dislocation densing region.With the spectra obtained in the dislocation free zone,the phonon peaks A1(Te precipitates),TO1(CdTe-like),TO2(ZnTe-like) are seen.Raman spectra obtained in dislocation densing region are consistent with A1 and TO1 modes,but TO2 peak disappeared.Further photolumince spectrum of CdZnTe crystal in dislocation densing region are investigated by photoluminescence microscopy with temperature from 10 K to 150 K.The results showed that the nonradiative recombination of electron-hole pairs absorb the energy of TO2 phonon,causing the lack of TO2 peak in Raman spectra obtained in dislocation densing region. |
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| Keywords: | CdZnTe dislocation Raman spectrum |
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