| Synthesis, Structure and Characterization of Two-dimensional Network Copper Complex [Cu_3(nta)_2(azpy)_2(H_2O)_2]·6H_2O |
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| 引用本文： | 李宝龙,徐艳,刘琦,王化勤,徐正. Synthesis, Structure and Characterization of Two-dimensional Network Copper Complex [Cu_3(nta)_2(azpy)_2(H_2O)_2]·6H_2O[J]. 中国化学, 2002, 20(2): 187-190. DOI: 10.1002/cjoc.20020200214 |
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| 作者姓名： | 李宝龙 徐艳 刘琦 王化勤 徐正 |
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| 作者单位： | LI，Bao Long XU，Yan LIU，Qi WANG，Hua Qin XU，ZhengInstitute of Coordination Chemistry，State Key Laboratory of Coordination Chemistry，Nanjing University，Nanjing 210093，China |
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| 基金项目： | theFoundationofKeyLaboratoryofOrganicSynthesesofJiangsuProvince (No.K9910 6 ) |
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| 摘 要： | ＩｎｔｒｏｄｕｃｔｉｏｎＣｒｙｓｔａｌｅｎｇｉｎｅｅｒｉｎｇｏｆｓｕｐｒａｍｏｌｅｃｕｌａｒａｒｃｈｉｔｅｃｔｕｒｅｓｓｕｓｔａｉｎｅｄｂｙｃｏｏｒｄｉｎａｔｅｃｏｖａｌｅｎｔｂｏｎｄｓｏｒｈｙｄｒｏｇｅｎｂｏｎｄｓｒｅｐｒｅｓｅｎｔｓａｒａｐｉｄｌｙｅｘｐａｎｄｉｎｇｆｉｅｌｄｔｈａｔｏｆｆｅｒｓｐｏ ｔｅｎｔｉａｌｆｏｒｄｅｖｅｌｏｐｍｅｎｔｏｆｎｅｗｃｌａｓｓｅｓｏｆｆｕｎｃｔｉｏｎａｌｓｏｌｉｄｓ .1,2 Ｔｈｅａｒｃｈｉｔｅｃｔｕｒｅｓｏｆｃｏｏｒｄｉｎａｔｉｏｎｐｏｌｙｍｅｒｓｃａｎｂｅ…
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Synthesis,Structure and Characterization of Two‐dimensional Network Copper Complex [Cu3(nta)2(azpy)2(H2O)2]·6H2O |
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| LI,Bao Long XU,Yan LIU,Qi WANG,Hua Qin XU,ZhengInstitute of Coordination Chemistry,State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing ,China. Synthesis,Structure and Characterization of Two‐dimensional Network Copper Complex [Cu3(nta)2(azpy)2(H2O)2]·6H2O[J]. Chinese Journal of Chemistry, 2002, 20(2): 187-190. DOI: 10.1002/cjoc.20020200214 |
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| Authors: | LI Bao Long XU Yan LIU Qi WANG Hua Qin XU ZhengInstitute of Coordination Chemistry State Key Laboratory of Coordination Chemistry Nanjing University Nanjing China |
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| Affiliation: | LI,Bao Long XU,Yan LIU,Qi WANG,Hua Qin XU,ZhengInstitute of Coordination Chemistry,State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing 210093,China |
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| Abstract: | The copper(II) complex[Cu3(nta)2(azpy)2(H2O)2]·6H2O (nta = nitrilotriacetate, azpy = 4,4′‐azobispyridine) has been synthesized and characterized. The X‐ray analysis reveals that there are two kinds of copper(II) coordination environments. Cu(1) has a distorted square plane symmetry and Cu(2) has a distorted octahedral symmetry. Cu(1) is linked to Cu(2) through nta and bound to Cu(1C) by azpy, and Cu(2) is linked to Cu(2A) through azpy, which extends to two‐dimensional network with large rhombus 1.2 nm × 1.7 nm. |
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| Keywords: | crystal structure two dimensional network copper complex azobispyridine |
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