Creep in macromolecular solutions according to rigid dumbbell kinetic theory |
| |
Authors: | R. B. Bird H. R. Warner Jr. |
| |
Affiliation: | 1. Chem. Engineering Dept. and Rheology Research Center, University of Wisconsin, 53706, Madison, Wisconsin, U.S.A.
|
| |
Abstract: | The creep experiment is analyzed using the rigid-dumbbell suspension model. It is found that the equilibrium shear compliance J e is given by $$J_e = frac{{theta _0 }}{{2eta _0^2 }} + O(kappa _infty ^2 )$$ where η0 and θ0 are the viscosity and primary normal stress functions at zero-shear rate, and κ ∞ is the velocity gradient for large time. It is found that, to the lowest level of approximation, τ yy ?τ zz and τ xx ?τ yy have the same sign during the creep experiment. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|