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高频介质阻挡放电烟气脱硫研究
引用本文:赵之骏,吴玉萍,张仁熙,侯惠奇. 高频介质阻挡放电烟气脱硫研究[J]. 化学学报, 2004, 62(23): 2308-2312
作者姓名:赵之骏  吴玉萍  张仁熙  侯惠奇
作者单位:复旦大学环境科学研究所,上海,200433;复旦大学环境科学研究所,上海,200433;复旦大学环境科学研究所,上海,200433;复旦大学环境科学研究所,上海,200433
摘    要:采用高频介质阻挡放电的方式产生低温等离子体,研究在不加入NH3的情况下流动态SO2的去除情况.实验表明,在输入电压为12 kV,SO2浓度为5400 mg/m3,气体流量为0.36 m3/h,相对湿度为55%时,脱硫率可达到70%以上;水气的存在对SO2的去除有较大的促进作用,升高电压和增加O2量对脱硫率的促进作用有限.对实验结果进行了解释,并提出了反应机理.

关 键 词:介质阻挡放电  脱硫  流动态  低温等离子体

Study of the Desulfurization by High Frequency Dielectric Barrier Discharge
ZHAO Zhi-Jun,WU Yu-Ping,ZHANG Ren-Xi,HOU Hui-Qi. Study of the Desulfurization by High Frequency Dielectric Barrier Discharge[J]. Acta Chimica Sinica, 2004, 62(23): 2308-2312
Authors:ZHAO Zhi-Jun  WU Yu-Ping  ZHANG Ren-Xi  HOU Hui-Qi
Affiliation:Institute of Environmental Science, Fudan University, Shanghai 200433
Abstract:The removal of flowing SO 2 was studied in the absence of NH 3 by cold plasma generated by high frequency dielectric barrier discharge. The results showed that the decomposition rate was over 70% at the experimental conditions of 12 kV input voltage and 55% relative humidity with the SO 2 concentration of 5400 mg/m 3 and the gas flux of 0 36 m 3/h. The added H 2O(g) played an important role in the SO 2 removal, and in addition, the increasing O 2 and input voltage exerted a little influence on the decomposition rate of SO 2. The desulfurization mechanism was also discussed under the analysis of experimental results.
Keywords:dielectric barrier discharge   desulfurization   flowing   cold plasma
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