Photocatalysis by ZnS nanoparticles of the formation of ZnS/Au heterostructure in the reduction of complex ions of gold |
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Authors: | A E Raevskaya A V Korzhak A L Stroyuk S Ya Kuchmii |
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Institution: | (1) L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky 31, 03028 Kyiv, Ukraine |
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Abstract: | The photocatalytic activity of ZnS nanoparticles during the reduction of the KAu(CN)2 complex was found. The spectral characteristics of the nanocomposite ZnS/Au0 and also the principal kinetic relationships involved in its formation were studied. It was shown that the photoreaction
has equilibrium character resulting from oxidation of the obtained gold by holes in the valence band of the zinc sulfide.
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Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 41, No. 6, pp. 343–347, November–December, 2005. |
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Keywords: | photocatalysis photochemical synthesis ZnS nanoparticles gold nanoparticles plasmon resonance |
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