| 非线性色谱保留时间与进样量关系的实验分析 |
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| 引用本文： | 欧锦如,郁蕴璐,林炳承,林炳昌.非线性色谱保留时间与进样量关系的实验分析[J].物理化学学报,1993,9(1):111-116. |
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| 作者姓名： | 欧锦如 郁蕴璐 林炳承 林炳昌 |
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| 作者单位： | Anshan Institute of Heat Energy Anshan; Dalian Institute of Chemmical Physics, Acadimia Sinica, Dalian 116023; Anshan Institute of Iran and Steel Tech nology, Anshan 114002 |
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| 摘 要： | 随着制备色谱的发展,对非线性色谱的研究日益深入,非线性色谱中保留时间与进样量的关系是非线性色谱研究中的重要课题.非线性色谱理论研究从40年代开始,主要工作是数学模型的求解与分析.结合理论的实验研究工作较少,关于非线性色谱中进样量与保留时间关系的研究更是这样.对于柱效为无限的理想情形,Aris 与Amundson 曾从理论上作过详细分析,在理想条件下,色谱方程为
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| 关 键 词： | 非线性色谱 保留时间 进样量 吸附等温线 激波 |
| 收稿时间： | 1991-08-19 |
| 修稿时间： | 1992-01-16 |
COMPARISION BETWEEN EXPERIMENT AND FORMULA RELATED THE RETENTION TIME TO INJECTION CONCENTRATION |
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| Ou Jinru.COMPARISION BETWEEN EXPERIMENT AND FORMULA RELATED THE RETENTION TIME TO INJECTION CONCENTRATION[J].Acta Physico-Chimica Sinica,1993,9(1):111-116. |
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| Authors: | Ou Jinru |
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| Institution: | Anshan Institute of Heat Energy Anshan; Dalian Institute of Chemmical Physics, Acadimia Sinica, Dalian 116023; Anshan Institute of Iran and Steel Tech nology, Anshan 114002 |
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| Abstract: | The experimental retention time obtained for a series of the different injectionWULI HUAXUE XUEBAO (Acta Phys.-Chim.)1993 concentration are compared to formula related the retention time to injection con-centration,which is derived from the nonlinear chromatography equation.The re-sults show that the theoretical formula is a appropriate approximation to the practicalnonliear chromatography. |
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| Keywords: | Nonlinear chromatography Retention time Isotherm Injection concentration Shock |
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