Zur Kenntnis des RbNiCrF6-Typs. V. Neue Fluoride CsBMF6 mit B = MnII bzw. NiII und M = Ga,Fe, Rh bzw. Sc,In, Tl,Rh |
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Authors: | R. R. Jesse R. Hoppe |
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Abstract: | On the RbNiCrF6 Type. V. New Fluorides of the Type CsBMF6 with B = MnII or NiII and M = Ga, Fe, Rh or Sc, In, Tl, Rh New prepared are the cubic compounds CsNiScF6 (light yellow, a = 10.60 Å); CsNiInF6 (lightyellow, a = 10.64 Å); CsNiTlF6 (light yellow, a = 10.60 Å); CsNiRhF6 (light redbrown, a = 10.37 Å); CsMnGaF6 (pink, a = 10.42 Å); CsMnFeF6 (light green, a = 10.55 Å) and CsMnRhF6 (redbrown, a = 10.58 Å), all RbNiCrF6 type of structure. The Madelung part of lattice energy, MAPLE, is calculated and discussed. |
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