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Dynamics of diatomic molecules confined in a chemical trap I. Nuclear magnetic resonance experiments on hydrogen in solid C60
Authors:M TOMASELLI
Institution:Physical Chemistry, Eidgen?ssische Technische Hochschule Zürich , CH-8093, Zürich, Switzerland
Abstract:A detailed nuclear magnetic resonance analysis of the low-temperature dynamics of hydrogen (H2, D2, and HD) trapped in a solid matrix of C60 is presented. Experimental evidence for hindered rotational and localized three-dimensional translational motion for hydrogen within the ‘box’ formed by the C60 molecules is given.
Keywords:
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