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Low resolution VUV absorption spectrum of boron monoxide
Authors:H. BREDOHL  J. BRETON  I. DUBOIS  J. M. ESTEVA  F. REMY
Affiliation:1. Institut d'Astrophysique et de Géophysique, Université de Liege , B-4000 , Liège , Belgium;2. LURE, Bàtiment 209 D, Université de Paris-Sud , F-91405 , Orsay , France;3. Equipe de Spectroscopie VUV, Université P. et M. , Curie, Case 81, 4, Place Jussieu, F-75252 , Paris , France;4. Laboratoire de Spectroscopie Atomique et Ionique , Université de Paris-Sud , Bàtiment 350, F-91405 , Orsay , France
Abstract:The absorption spectrum of BO has been recorded between 2400 and 300 Å on the SA61 beam line of SUPERACO in Orsay. A new electronic transition has been observed and vibrationally analysed. Nine Rydberg states have been observed and classified into Rydberg series giving two ionization limits at 12.849eV for the X 1Σ+ ionic state and at 13.117eV for the A 1II state of BO+. Two ionization limits have been observed at 754 and 374 Å. The first of these corresponds to the B 1Σ+ state and the last one to the C 1Σ+ state of BO+. The new results are compared with the ab initio calculations of Karna and Grein concerning BO and BO+. The agreement is satisfactory.
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