Non-adiabatic transitions for random processes in a two-level system |
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Authors: | I.V. Alexandrov L.G. Karamjan |
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Affiliation: | Institute of Chemical Physics, Academy of Sciences of the USSR , Moscow |
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Abstract: | Non-adiabatic transitions in two-level systems are investigated theoretically for a random time dependence of ?ω, the energy difference, between the levels. We assumed that ω = ω(x) and the coordinate x = x(t) is a random function of time. Diffusion and Poisson processes (both homogeneous and with a source) for x(t) were assumed. The cases of linear crossing terms (ω = γx) and non-linear terms (ω = ω e exp (- αx) + ω0) were considered. Values of the non-adiabatic transition probability per unit time were obtained by perturbation theory for ω1τ c ? 1 where τ c is the correlation time and ω1 is the off-diagonal matrix element. |
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