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Virial series around non-null density: density dependence of virial coefficients
Authors:I. URRUTIA  J. A. HERNANDO
Affiliation:1. Department of Physics , Comisión Nacional de Energía Atómica , Av. del Libertador 8250, 1429, Buenos Aires, Argentina;2. Comisión de Investigaciones Científicas de la Provincia de Buenos Aires , 526 e/10 y 11, 1900 La Plata, Buenos Aires, Argentina;3. Department of Physics , Comisión Nacional de Energía Atómica , Av. del Libertador 8250, 1429, Buenos Aires, Argentina
Abstract:It is shown that the equation of state of fluid systems can be expanded around non-null densities if the well known virial series is generalized by considering its coefficients as density dependent. This in turn leads to a hierarchy of differential equations that describe the coefficients bj (ρ). Starting from the already known equation of state for hard bodies in d = 0,1,2,3 dimensions this hierarchy is analysed and the behaviour of both the reducible bj (ρ) and irreducible β~ j (ρ) cluster integrals is discussed. New virial coefficients bj (ρ) have been introduced with a simpler density dependence. Their asymptotic (j → ∞) behaviour is discussed.
Keywords:
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