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Calculation of vibrational relaxation times in gaseous cyanogen
Authors:P.G. Dickens
Affiliation:Inorganic Chemistry Laboratory , Oxford
Abstract:A calculation of vibrational relaxation times in gaseous cyanogen at 300°K is presented. It is suggested that two well separated dispersion regions should be found in sound velocity measurements at ultrasonic frequencies, the higher frequency region being associated with the relaxation of the combined vibrational specific heat contributions of the two lowest modes and the lower frequency region being associated with the relaxation of the corresponding contribution of the next highest mode.
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