Surface Chemistry of Polyacetylene: Adhesion to Silica,Derivatization With Nickel And Catalytic Activity |
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| Authors: | Duncan H. Whitney Gary E. Wnek |
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| Affiliation: | 1. Department of Materials Science &2. Engineering , Massachusetts Institute of Technology , Cambridge, MA, 02139, USA |
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| Abstract: | Adhesion of (CH)x film prepared by the Luttinger method to glass can be improved by silylation in order to more closely match dispersive surface energies. Treatment of n-type (CH) films with NiBr2/HMPA/THF affords (CH)x -supported N° which shows selectivity in hydrogenation of phenyl acetylene. |
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