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Synthesis and Some Properties of Low Melting Ferroelectric Liquid Crystals of Benzylidene Anilines
Authors:Teruo Kitamura  Akio Mukoh  Masato Isogai  Takashi Inukai  Kenji Furukawa  Kanetsugu Terashima
Institution:1. Hitachi Research Laboratory, Hitachi Ltd. , 4026 Kuli, Hitachi, lbaraki, 319-12, Japan;2. Chisso Corporation , 2 Kamariya, Kanazawa-ku, Yokohama, 236, Japan
Abstract:A series of chiral benzylidene-aniline compounds, 4-alkoxybenzylidene 4′-(2-methylbutyloxycarbonyl)anilines, have been synthesized and their mesomorphic properties are examined. They showed a monotropic chiral smectic C phase in conjunction with enantiotropic smectic A phase, and their chiral smectic C—smectic A phase transition temperatures are around room temperatures. Their spontaneous polarization values are moderately higher than those of DOBAMBC “4-decyloxybenzylidene 4′-amino-(2-methylbutyl)cinnamate”.
Keywords:ferroelectric liquid crystal  chiral smectic C phase  benzylideneaniline  mesomorphic range  low melting
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