The line shapes of a tumbling triplet |
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Authors: | J. Roberts R.M. Lynden-Bell |
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Affiliation: | 1. Chemical Laboratory , University of Sussex , Brighton, BN1 9QJ;2. Chemical Laboratory , University of Southampton |
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Abstract: | The line shapes of a triplet spin system which interacts simultaneously with the molecular environment and with an externally applied field depend on the relative strengths of these interactions and on the motion of the molecule relative to the laboratory. In this paper line shapes are reported for zero, low, intermediate and strong applied fields, assuming that the molecular motion is due to strong collisions and that the tumbling rate is slow or intermediate. |
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