Self-Assembly and Phase Behavior of Short Chain Phosphonic Acid-Water Systems in a Wide Concentration Range Microscopic,NMR, and X-ray Diffraction Studies |
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| Authors: | G. Klose A. G. Petrov F. Volke H. W. Meyer G. Förster W. Rettig |
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| Affiliation: | 1. Department of Physics , Karl Marx University , 7010, Leipzig, GDR;2. Department of Physics , Karl Marx University , 7010, Leipzig, GDR;3. Medical Department , Institute of Pathology, Friedrich Schiller University , Jena, GDR;4. Department of Chemistry , Martin Luther University , Halle, GDR;5. Department of Chemistry , Martin Luther University , Halle, GDR;6. Department of Physics , Karl Marx University , 7010, Leipzig, GDR;7. Liquid Crystal Group , Institute of Solid State Physics, Bulgarian Academy of Sciences , Sofia, 1184, Bulgaria |
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| Abstract: | The phase behavior of n-octane and n-hexane phosphonic acid-D2O systems was studied in the concentration range from 0.1 to 90 wt.% and in a temperature range from 10° to 130°C by polarizing and dark field microscopy and by 1H, 2D and, 31P NMR. Further, electron microscopy, X-ray diffraction and surface tension measurements were performed. For the first time, a widely spaced lamellar phase was observed over large concentration and temperature ranges in an essentially two-component system. By using the sonication or injection methods, unilamellar liposomes were obtained below 1 wt.%. At high temperatures, the clouding phenomenon was observed. The importance of hydrogen bond formation between polar groups for building up stable lamellae even at high dilution is stressed. The results are discussed with respect to some existing points of view concerning the possibility of lamellar structure formation from single short chain amphiphilic compounds including lipids. |
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