Electron spin resonance of photolytically reduced pyrazine |
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| Authors: | Henry Zeldes Ralph Livingston |
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| Institution: | Chemistry Division , Oak Ridge National Laboratory , Oak Ridge, Tennessee, 37830 |
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| Abstract: | A mapping between the exactly soluble forced oscillator and the general vibrationally inelastic scattering problem is shown to yield a new uniform approximation based on generalized Laguerre polynomials. Computations are reported for collinear He-H2 collisions in which H2 is represented by harmonic and Morse oscillators. The results show that the Laguerre approximation avoids the known failings of the existing Airy and Bessel uniform approximations. |
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