High CO2 uptake and selectivity by triptycene-derived benzimidazole-linked polymers |
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Authors: | Rabbani Mohammad Gulam Reich Thomas E Kassab Refaie M Jackson Karl T El-Kaderi Hani M |
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Affiliation: | Department of Chemistry, Virginia Commonwealth University, Richmond, VA 23284-2006, USA. |
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Abstract: | Successful incorporation of triptycene into benzimidazole-linked polymers leads to the highest CO(2) uptake (5.12 mmol g(-1), 273 K and 1 bar) by porous organic polymers and results in high CO(2)/N(2) (63) and CO(2)/CH(4) (8.4) selectivities. |
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