Electronic spectra of α,β-unsaturated ketones — Indole derivatives |
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Authors: | S V Tsukerman A I Bugai V F Lavrushin |
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Institution: | (1) A. M. Gorkii Kharkov State University, USSR |
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Abstract: | The electronic spectra of (3-indolyl)-, (1-methyl-3-indolyl)-, and (6-nitro-3-indolyl)-substituted , -unsaturated ketones were measured and interpreted. 3-Indolyl and N-methyl-3-indolyl substituents have a considerable bathochromic effect as compared with the phenyl group in the investigated systems as a consequence of the electron-donor effect, which surpasses that for 4-anisyl, 2,4-dimethoxyphenyl, 2-furyl, 2-thienyl, and 2-selenienyl and differs only slightly from 2-pyrrolyl. The introduction of electron-donor substituents into the p position of the benzene ring of 1-(3-indolyl)-3-phenyl-1-propenone causes a red shift of the long-wave absorption band, the difference in frequencies of which correlates with the Hammett substituent constants. Except for compounds containing a nitro group,1-(3-indolyl)-3-aryl-3-propenones and their N-methyl derivatives fluoresce well in alcohol with
max >475 nm.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 949–953, July, 1972. |
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