| 二茂铁-磷钼酸电荷转移配合物修饰电极的制备及电化学性能的研究 |
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| 引用本文： | 杜丹,王升富.二茂铁-磷钼酸电荷转移配合物修饰电极的制备及电化学性能的研究[J].分析科学学报,2001,17(1):21-24. |
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| 作者姓名： | 杜丹 王升富 |
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| 作者单位： | 湖北大学化学与材料科学学院, |
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| 摘 要： | 采用电化学方法在异电基体玻碳（GC）电极上制备了二茂铁 （Fc）－磷钼酸（PMo12）电荷转移配合 物修饰电极（Fe5PMo12/GC)。研究了该电极的电化学行为，发现其在硫酸溶液中进行伏安扫描时具有良好的稳定性，而且对酸性水溶液中的过氧化氢具有较好的电催化学原作用， 初步探讨了电催化还原机理。
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| 关 键 词： | 二茂铁－磷钼酸电荷转移配合物 过氧化氢 化学修饰电极 电催化还原 制备 |
| 文章编号： | 1006-6144(2001)01-0021-04 |
| 修稿时间： | 1999年11月26 |
The Preparation and Its Voltammetric Behaviours of Ferrocenc Dicyclopentadienyl-Molybdophosphoric Heterpoly Acid Charge-Transfer Coordination Compound Film Modified Electrode |
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| DU Dan,WANG Sheng fu.The Preparation and Its Voltammetric Behaviours of Ferrocenc Dicyclopentadienyl-Molybdophosphoric Heterpoly Acid Charge-Transfer Coordination Compound Film Modified Electrode[J].Journal of Analytical Science,2001,17(1):21-24. |
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| Authors: | DU Dan WANG Sheng fu |
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| Institution: | DU Dan,WANG Sheng fu * |
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| Abstract: | Ferrocenc dicyclopentadienyl molybdophosphoric heterpoly acid charge transfer coordination compound film modified glassy carbon electrodes have been prepared by electrochemical deposition and their voltammetric behavior were studied. The modified electrodes had good stability in sulfuric acid and high electrocatalytic activity towards the reduction of hydrogen peroxide in acid aqueous solution. The catalytic process was described. |
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| Keywords: | Ferrocenc dicyclopentadienyl molybdophosphoric heterpoly acid change transfer coordination compound Hydrogen peroxide Chemistry modified electrodes Electrocatalytic reduction |
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