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Synthesis of Cubic Mesoporous Silica MCM-48by Mixed Micellar Templates
作者姓名:Tong Wen WANG    Le Rong DAI * Institute of Physical Chemistry  Peking University  Beijing
作者单位:Tong Wen WANG 1,2,Le Rong DAI 1 * 1Institute of Physical Chemistry,Peking University,Beijing 100871 2Department of Chemistry,Yunnan Normal University,Kunming 650092
基金项目:the State Key Program Foundation of China !(97021107),The National Natural Science Foundation of China !(29992590-4).
摘    要:In 1992, Mobil researchers introduced a novel concept in the synthesis of mesoporous silicas (M41S)1,2 by using a self-assembled molecular array of surfactant molecules as structure-directing template. Depending on the shape of their templates and the respective resulting pore structure, the M41S family was identified : MCM-41(hexagonal), MCM-48(cubic), and other species. MCM-41 with honeycomb arrays of nonintersecting channels was shown to be the easiest to synthesize1. MCM-48 containin…


Synthesis of Cubic Mesoporous Silica MCM-48 by Mixed Micellar Templates
Tong Wen WANG ,,Le Rong DAI * Institute of Physical Chemistry,Peking University,Beijing .Synthesis of Cubic Mesoporous Silica MCM-48by Mixed Micellar Templates[J].Chinese Chemical Letters,2000,11(12).
Authors:Tong Wen WANG  Le Rong DAI
Abstract:High-quality mesoporous silica MCM-48 were synthesized under basic conditions by using the mixture of cetyltrimethylammonium bromide (CTAB) and alkylamine (CnNH2n+3, n=8,10,12,14, respectively) as templates. The effects of the alkylamines with different chain lengths (n=8,10,12,14,16,18, respectively) on the silica structure were investigated.
Keywords:Mixed micellar template  cubic mesoporous silica  synthesis  
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