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Synthesis of new CF3-containing 3,4-dihydro-2H-pyrans
Authors:Krasovsky  A. L.  Nenajdenko  V. G.  Balenkova  E. S.
Affiliation:(1) Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899 Moscow, Russian Federation
Abstract:The reactions of vinyl sulfides with beta-sulfonylvinyl trifluoromethyl ketones afforded CF3-containing 3,4-dihydro-2H-pyrans. An attempt to synthesize 1,1,1-trifluoro-3-(methylthio)but-3-en-2-one resulted in its dimerization into a CF3-containing 3,4-dihydro-2H-pyran.
Keywords:trifluoromethyl ketone  vinyl sulfides  3,4-dihydro-2H-pyrans  the hetero-Diels—  Alder reaction
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