| 自组装单分子膜在电化学电子转移过程中的应用 |
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| 引用本文： | 邵会波,宋雅茹,王宁,童汝亭.自组装单分子膜在电化学电子转移过程中的应用[J].分析化学,2003,31(7):874-879. |
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| 作者姓名： | 邵会波 宋雅茹 王宁 童汝亭 |
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| 作者单位： | 1. 首都师范大学化学系,北京,100037
2. 北京师范大学化学系,北京,100857 |
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| 基金项目： | 国家自然科学基金 (No .2 9973 0 2 6)，北京市自然科学基金 (No .2 992 0 0 7)，教育部高等学校骨干教师资助项目 |
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| 摘 要： | 综述了自组装单分子膜作为模型体系在电化学电极过程中长程电子转移方面应用的一些重要研究成果。重点介绍了电子转移距离、电活性中心的微环境、膜表面分子的设计和状态等因素对长程电子转移的影响情况。展望了该领域今后的发展方向。
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| 关 键 词： | 自组装单分子膜 电化学 电子转移 电极过程 膜表面分子 电子遂穿系数 |
Applications of Self-Assembled Monolayers in Electrochemical Electron Transfer Kinetics |
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| Shao Huibo ,Song Yaru,Wang Ning,Tong Ruting.Applications of Self-Assembled Monolayers in Electrochemical Electron Transfer Kinetics[J].Chinese Journal of Analytical Chemistry,2003,31(7):874-879. |
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| Authors: | Shao Huibo Song Yaru Wang Ning Tong Ruting |
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| Institution: | Shao Huibo *1,Song Yaru2,Wang Ning1,Tong Ruting1 1 |
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| Abstract: | Self-assembled monolayers (SAMs) present an ideal model for the studies of electrochemical electron transfer kinetics. In this paper, some important results in this field, especially some effect factors, such as the distance of electron transfer, the design of film molecules and structure, and the microenvironment of redox active species, on the electron transfer kinetics, are reviewed. The future directions of applications of SAMs in electrochemical electron transfer kinetics are also given. |
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| Keywords: | Self-assembled monolayers long range electron transfer electron tunnelling constant review |
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