Concentration dependence and effect of oxygen on the primary phototrans-formation processes of khinifur |
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| Authors: | N K Tatarskaya M A Zhurav S M Smirnov I A Degterev V F Tarasov Yu E Borisevich G E Zaikov |
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| Institution: | 1. N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow
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| Abstract: | | 1. |
The decomposition of khinifur in aqueous solutions proceeds according to two parallel paths: direct photodecomposition from the first singlet activated state (monomolecular path) and reaction of the molecule in the triplet state with a molecule in the initial state (bimolecular path).
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The first path does not depend on the pressure of oxygen in the solution, while the second path is inhibited by oxygen.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 804–809, April, 1989. |
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