The first beta-diketiminate-Ag(I) complexes. Macrocyclic dinuclear and tetranuclear Ag(I)-complexes and linear coordination polymer Ag(I)-complex |
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| Authors: | Shimokawa Chizu Itoh Shinobu |
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| Affiliation: | Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan. |
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| Abstract: | Reactions of Ag(I) and a series of beta-diketiminate ligands have been investigated to demonstrate that unique macrocyclic dinuclear and tetranuclear Ag(I)-complexes and a linear coordination polymer Ag(I)-complex as well as oxidative C-C coupling dimer products of the ligands were obtained depending on the substituents on the carbon framework of beta-diketiminate ligands. |
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