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Double Molecular Encapsulation of Tetrahydrofuran by an Amphiphilic Calix-[4]-arene
Authors:Patrick?Shahgaldian,Anthony?W.?Coleman  author-information"  >  author-information__contact u-icon-before"  >  mailto:aw.coleman@ibcp.fr"   title="  aw.coleman@ibcp.fr"   itemprop="  email"   data-track="  click"   data-track-action="  Email author"   data-track-label="  "  >Email author,Beth?Rather,Michael?J.?Zaworotko
Affiliation:(1) Institut de Biologie et Chimie des Proteines, CNRS UMR5086, 7 Passage du Vercors, Lyon, F69367, France;(2) Department of Chemistry, University of South Florida, 4202 E Fowler Ave (SCA 400), Tampa, FL 33620, USA
Abstract:The crystal structure of para-octanoylcalix-[4]-arene·2 tetrahydrofuran complex reveals double inclusion of the guest molecules, one deep in the aromatic cavity and the other held in a four-fingered molecular hand formed by the aliphatic chains, the inclusion changes the molecular packing from a bilayer system in the absence of guest, to a head-to-tail antiparallel chain packing.This revised version was published online in July 2005 with a corrected issue number.
Keywords:amphiphilic  calix-[4]-arene  crystal structure  double inclusion  tetrahydrofuran
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